Some can be, yes. Most molds cause allergies that are uncomfortable but not life-threatening. However, all can be dangerous for people with asthma, compromised immune systems, the young or the aged. A few are toxic to humans or can cause infections.
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Most stain is applied with a brush, a roller, or spraying. The manufacturer's instructions will advise the best method to suit your chosen stain.
Your wood must be clean and dry. That means all dirt and residual paint should be removed by washing and scraping. If you want a smoother surface, you can sand the wood, which helps remove dirt and...