If you’ve seen this term on an epoxy label, it’s just an industry term. It indicates the total working time from the moment you mix it until the moment it becomes unusable. A lot of things can affect pot life (like temperature, the exact formula of the product, and quantity), so you can’t always trust these values. Still, it will give you a general idea of how much time you will have.
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Most stain is applied with a brush, a roller, or spraying. The manufacturer's instructions will advise the best method to suit your chosen stain.
Your wood must be clean and dry. That means all dirt and residual paint should be removed by washing and scraping. If you want a smoother surface, you can sand the wood, which helps remove dirt and...