It depends on the type and condition of wood that we are using. There is no one answer to what comes first, but it is good to sand and cleans the surface before starting with anything else.
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Most stain is applied with a brush, a roller, or spraying. The manufacturer's instructions will advise the best method to suit your chosen stain.
Your wood must be clean and dry. That means all dirt and residual paint should be removed by washing and scraping. If you want a smoother surface, you can sand the wood, which helps remove dirt and...