Yes, you must prime bare wood before painting. The purpose of primer is to make the wood less porous. It is the layer that adheres the paint to the wood. I recommend priming wood before painting it as it provides a smooth and clean area for the paint to adhere to.
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Most stain is applied with a brush, a roller, or spraying. The manufacturer's instructions will advise the best method to suit your chosen stain.
Your wood must be clean and dry. That means all dirt and residual paint should be removed by washing and scraping. If you want a smoother surface, you can sand the wood, which helps remove dirt and...